Ultrafast Observation of a Photoredox Reaction Mechanism: Photoinitiation in Organocatalyzed ATRP
Abstract: Photoredox catalysis has driven a revolution in the field of organic chemistry, but direct mechanistic insights into reactions...
Abstract: Photoredox catalysis has driven a revolution in the field of organic chemistry, but direct mechanistic insights into reactions...
Abstract: Using a phenoxazine-based organic photosensitizer and an iron porphyrin molecular catalyst, we demonstrated photochemical...
Abstract: A signature of photo‐mediated controlled polymerizations is the ability to modulate the rate of polymerization by turning the...
Abstract: Organocatalyzed atom transfer radical polymerization (O-ATRP) was performed under air using core modified N-aryl phenoxazines...
Abstract: C–N cross-coupling is an important class of reactions with far-reaching impacts across chemistry, materials science, biology,...
Abstract: A key feature of prominent transition-metal-containing photoredox catalysts (PCs) is high quantum yield access to long-lived...
Abstract: Disclosed is a mild, scalable, visible-light-promoted cross-coupling reaction between thiols and aryl halides for the...
Abstract: Through the study of structure–property relationships using a combination of experimental and computational analyses, a number...
Abstract: Photoredox catalysis is a versatile approach for the construction of challenging covalent bonds under mild reaction conditions,...
Abstract: Organic photoredox catalysts have been shown to operate organocatalyzed atom transfer radical polymerizations (O-ATRP) using...
Abstract: The recent development of organocatalyzed atom transfer radical polymerization (O‐ATRP) represents a significant advancement...
Abstract: The nature of intramolecular charge transfer (CT) of N,N‐diaryl dihydrophenazine photocatalysts (PCs) in different solvents is...
Abstract: Photoexcited intramolecular charge transfer (CT) states in N,N-diaryl dihydrophenazine photoredox catalysts are accessed...